Monitoring and Exposure Assessment of Fosetyl Aluminium and Other Highly Polar Pesticide Residues in Sweet Cherry

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dc.authorid0000-0001-7816-6308
dc.authorid0000-0001-6047-4302
dc.authorid0000-0001-6550-3627
dc.contributor.authorGormez, Emrah
dc.contributor.authorGolge, Ozgur
dc.contributor.authorAngel Gonzalez-Curbelo, Miguel
dc.contributor.authorKabak, Bulent
dc.date.accessioned2026-01-24T12:26:35Z
dc.date.available2026-01-24T12:26:35Z
dc.date.issued2023
dc.departmentAlanya Alaaddin Keykubat Üniversitesi
dc.description.abstractCherries are popular fruits due to their health benefits, organoleptic quality, and attractive appearance. Since highly polar pesticides are of low mass and amphoteric character, and are not amenable to traditional multi-residue extraction methods, they are more commonly not included in the pesticide monitoring program. This study aims to determine twelve highly polar pesticide residues in cherry samples intended for export from Turkey. A total of 16,022 cherry samples from 2018-2020 harvests in four production areas of Turkey were analyzed using a modification of the Quick Polar Pesticides method and liquid chromatography-tandem mass spectrometry. The method was validated at two fortification levels (0.01 and 0.05 mg kg(-1)), and good recoveries (87.4-111.4%) and relative standard deviations (<6%) were achieved for all analytes. The limits of quantification were in the range of 1.08-2.55 mu g kg(-1). Overall, 28.4% of the analyzed cherry samples were detected with phosphonic acid, calculated as fosetyl aluminium (fosetyl-Al) in amounts up to 77.7 mg kg(-1). For 2304 samples (14.4%), the residues exceeded the European Union maximum residue level of 2 mg kg(-1). There is no reason to be concerned about long-term exposure to phosphonic acid/fosetyl-Al, and the other highly polar pesticides through the consumption of sweet cherry.
dc.identifier.doi10.3390/molecules28010252
dc.identifier.issn1420-3049
dc.identifier.issue1
dc.identifier.pmid36615450
dc.identifier.scopus2-s2.0-85145750161
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.3390/molecules28010252
dc.identifier.urihttps://hdl.handle.net/20.500.12868/4779
dc.identifier.volume28
dc.identifier.wosWOS:000908700400001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherMdpi
dc.relation.ispartofMolecules
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WoS_20260121
dc.subjectanalytical method validation
dc.subjectchromatography
dc.subjectfood safety
dc.subjectmass spectrometry
dc.subjectpolar pesticides
dc.subjectrisk assessment
dc.titleMonitoring and Exposure Assessment of Fosetyl Aluminium and Other Highly Polar Pesticide Residues in Sweet Cherry
dc.typeArticle

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