A new entropy function to analyze isentropic processes of ideal gases with variable specific heats

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Tarih

2022

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Dergi ISSN

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Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

A new entropy function s + is defined in terms of the existing entropy function s ? and temperature as s + = s ? ? R lnT to facilitate the analysis of isentropic processes of ideal gases with variable specific heats. The function s+ also makes it possible to calculate the entropy changes of ideal gases during processes when volume information is available instead of pressure information and the variation of specific heats with temperature is to be accounted for. The introduction of the function s + eliminates the need to use the dimensionless isentropic functions relative pressure Pr and relative specific volume vr of ideal gases and to tabulate their values. The Pr and vr data are often confused with pressure and specific volume, with an adverse effect on the study of the second law of thermodynamics. The new s + function nicely complements the existing s ? function in entropy change calculations: the former is conveniently used when volume information is given while the latter is used when pressure information is available. Therefore, the introduction of the new entropy function s + is expected to make a significant contribution to the thermodynamics education and research by streamlining entropy analysis of ideal gases.

Açıklama

Anahtar Kelimeler

thermodynamics, entropy, entropy function, isentropic process, ideal gases, variable specific heats, second-law analysis

Kaynak

Entropy

WoS Q Değeri

N/A

Scopus Q Değeri

Cilt

24

Sayı

746

Künye