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    Adsorption of AR114 onto humic acid-modified Fe3O4 nanoparticles
    (Inst Natl Cercetare-Dezvoltare Textile Pielarie-Bucuresti, 2023) Kaykioglu, Guel; Bayramol, Derman vatansever; Yildiz, Aylin
    In this study, Fe3O4 and humic acid-modified Fe3O4 (Fe3O4@HA) magnetic nanoparticles were synthesized and used for the removal of Acid Red 114 (AR114) dyestuff from aqueous. The batch adsorption method was used for the experiments. The magnetic nanoparticles, synthesised by an inexpensive and environmentally friendly precipitation process, were characterised by FTIR, SEM-EDX, BET surface area, and XRD analyses. The optimum pH values determined for Fe3O4 and Fe3O4@HA were the original pH (6.4) and 4, respectively. The equilibrium state was reached after 60 minutes for both adsorbents. The values for Fe3O4 and Fe3O4@HA were determined as 3.4 mg/g and 3.1 mg/g, respectively, when 10 mg/l initial dyestuff concentration and 2 g adsorbent were used. The results obtained in the adsorption experiments performed for both adsorbents were compatible with the Freundlich isotherm and pseudo-second-order kinetic model. Fe3O4 was found to be more efficient than Fe3O4@HA in terms of reuse and Fe3O4 can be used 5 times without any significant loss of adsorption capacity. The results showed that Fe3O4 and Fe3O4@HA can be environmentally friendly alternative adsorbents for the removal of hazardous azo dyestuffs from water, and have regeneration possibilities.
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    COMPARATIVE INVESTIGATION OF Fe3O4, Fe3O4@HA AND Fe3O4@AC NANOPARTICLES ON DYES ADSORPTION
    (Gh Asachi Technical Univ Iasi, 2022) Kaykioglu, Gul; Yildiz, Aylin; Bayramol, Derman Vatansever; Dalmis, Ibrahim Savas; Miral, Iskender Tamer
    In this study, the removal of Methylene Blue (MB) and Methyl Orange (MO) dyestuffs from aqueous solutions via adsorption by using magnetic nanoparticles of Fe3O4, Fe3O4@HA and Fe3O4@AC synthesized under laboratory conditions was investigated. The synthesized magnetic nanoparticles were characterized by SEM, EDX, XRD, BET surface area, FTIR, average pore diameter and particle size distribution analysis. When Fe3O4, Fe3O4@HA and Fe3O4@AC were used as adsorbents, the optimum pH values for MB were determined as pH 11, pH 9 and pH 7, respectively, and pH 6, pH 4 and pH 4 for MO, respectively. At the determined optimum pH values, Fe3O4, Fe3O4@HA and Fe3O4@AC were determined to be 4.2 mg/g, 4.8 mg/g and 8 mg/g for MB at an initial dye concentration of 10 mg/L, while Fe3O4, Fe3O4@HA and Fe3O4@AC were determined to be 3 mg/g, 1.6 mg/g and 4.5 mg/g for MO, respectively. It was found to be compatible with the Freundlich isotherm and pseudo second-order model of all adsorption experiments. This study showed that Fe3O4@HA, synthesized by binding HA to Fe3O4, and Fe3O4@AC, synthesized, and carbonized by pyrolysis, magnetic nanoparticles can be used as a good alternative adsorbent for removing hazardous dyes from wastewater due to their good cleaning efficiency as well as easy synthesis and regeneration.
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    From industrial waste to carbon-containing nanocomposites to obtain multifunctional properties for industrial applications
    (Elsevier, 2022) Yildiz, Aylin; Acikbas, Burcu; Atav, Riza; Dalmis, Ibrahim Savas; Bayramol, Derman Vatansever; Bugdayci, Burhan
    Helianthus annuus (sunflower) and Brassica napus (canola) are two important crops for vegetable oil industry, but their residues after harvesting cause agricultural waste. In this study, agricultural wastes of sunflower and canola were utilized as activated carbon (AC) after pyrolysing the wastes at 450 degrees C and activating with HNO3 at 90 degrees C. Obtained AC was then used to produce Fe3O4@AC nanocomposites and beta-cyclodextrin(CD):Fe3O4@AC complex structures. Structural, morphological, spectroscopic, and thermal characteristic properties of the obtained nanocomposites and complex structures were examined by X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Fourier transform infrared (FTIR) and Thermogravimetric Analysis (TGA), respectively. Produced nanocomposites and complex structures were coated onto cotton woven fabrics which were then tested for their UV protection, flame retardant and antibacterial activity. The test results of the coated fabrics and the control (uncoated cotton fabric) samples showed that Fe3O4@AC and CD:Fe3O4@AC coated fabrics showed significant UV protection, flame retardancy and antibacterial properties. Thus, the effects which would normally be obtained with 3 different finishing chemicals, each of which causes individual waste load, were achieved with a single chemical recycled from a waste. This work is critical in terms of waste management and providing a cleaner production alternative in the field of textile finishing.
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    Inclusion complexes of ?-cyclodextrıne with Fe3O4@HA@Ag Part II: Their use in the production of PVP nanowebs
    (Inst Natl Cercetare-Dezvoltare Textile Pielarie-Bucuresti, 2023) Atav, Riza; Agirgan, Ahmet Ozgur; Yildiz, Aylin; Bayramol, Derman Vatansever; Erguenay, Ugur
    Humic acid is a material formed as a result of the degradation of animal and plant wastes, it cleans heavy metals which are industrial wastes that threaten both the environment and human health. In part I of this study, the Fe3O4@HA@Ag compound was synthesized, its inclusion complex with beta-cyclodextrin was prepared by using the kneading technique and obtained inclusion complexes were characterized. In this study, part II, nanowebs were formed from the inclusion of complex-containing polymer solution via the electrospinning method. The electrospinning solution consisted of beta-CD:Fe3O4@HA@Ag inclusion complexes at the rate of 5%, 7.5% and 10% by weight and the polyvinylpyrrolidone (PVP) polymer as the carrier. The obtained nanoweb material was characterized by instrumental methods such as SEM, FTIR, XRD, and TGA. The results obtained from FTIR, XRD and TGA revealed that beta-CD:Fe3O4@HA@Ag inclusion complexes containing nanowebs were successfully produced. The uniform fibre formation was detected from SEM images. The average fibre diameter of 5%, 7.5% and 10% beta-CD:Fe3O4@HA@Ag inclusion complex containing nanowebs were measured to be 612.5 nm, 610.8 nm and 431.2 nm, respectively.